Heirtzler, Fenton R., Santi, Saverio, Howland, Kevin, Weyhermüller, Thomas (2006) Formation of a solubilized cobalt block oligomer from a M\(_2\)L-type double helicate. Dalton Transactions, (39). pp. 4722-4729. ISSN 1477-9226. (doi:10.1039/B605512E) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:34170)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1039/B605512E |
Abstract
The multi-dentate ligand, 2,3,5,6-tetrakis(2,2'-bipyridyl)pyrazine (L) and divalent cobalt self-assemble to a block co-polymer-like oligomer in solution, which contains at least the L(7)Co(8) fragment. The extent of oligomerization is sensitive to the water content in acetonitrile solution. In the solid state, the simple monomer [LCo(2)(CH(3)CN)(4)][ClO(4)](4) is isolated. The X-ray structure of the crystallized material (containing four CH(3)CN solvate molecules) reveals a double-helical complex with two heptadentate Co(II) sites, and a helical pitch of approximately 28.1 A. Coupled Co(I/II) redox processes are observed between the two metal centres.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/B605512E |
| Subjects: | Q Science |
| Divisions: | Divisions > Division of Natural Sciences > Biosciences |
| Depositing User: | Kevin Howland |
| Date Deposited: | 15 May 2020 14:54 UTC |
| Last Modified: | 16 Nov 2021 10:11 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/34170 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Howland, Kevin.
| Creator's ORCID: |
 https://orcid.org/0000-0003-4370-0974
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