Synthesis and characterization of poly(methylphenylsilylene)-poly(ethylene oxide) and poly(methylphenylsilyiene)-polyisoprene multiblock copolymers

Hiorns, Roger C., Holder, Simon J., Schue, Francois, Jones, Richard G. (2001) Synthesis and characterization of poly(methylphenylsilylene)-poly(ethylene oxide) and poly(methylphenylsilyiene)-polyisoprene multiblock copolymers. Polymer International, 50 (9). pp. 1016-1028. ISSN 0959-8103. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:2543)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.

Abstract

Multiblock copolymers were synthesized through condensation reactions of end-groups of a,co-dichloro-poly(methylphenylsilylene) with hydroxyl end-groups of poly(ethylene glycol) or the chain-ends of 'living' polyisoprenyl disodium. Optimum conditions have been sought through kinetic studies and by investigation of model reactions. The overall molecular weight distribution of poly(methylphenylsilylene)-block-poly(ethylene oxide) is characterized in terms of Flory's theory of condensation reactions, while the limiting step in the reaction is tentatively attributed to the formation of aggregates. (C) 2001 Society of Chemical Industry.

Item Type:	Article
Additional information:	37 JOHN WILEY & SONS LTD
Uncontrolled keywords:	multiblock copolymer; poly(methylphenylsilylene); poly(ethylene oxide); polyisoprene; polycondensation BLOCK-COPOLYMERS; COUPLING REACTION; MOLECULAR-WEIGHT; HIGH POLYMERS; POLYSILANE; POLYMERIZATION; POLYMETHYLPHENYLSILANE; POLYSTYRENE
Subjects:	Q Science > QD Chemistry
Divisions:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Simon Holder
Date Deposited:	26 Jun 2008 14:36 UTC
Last Modified:	16 Nov 2021 09:41 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/2543 (The current URI for this page, for reference purposes)

University of Kent Author Information

Holder, Simon J..

Creator's ORCID:	https://orcid.org/0000-0001-8977-9257
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