Coordination of copper and silver by [co2(mu-c2(ch2sch2ch2)2s)(co)6]

Demirhan, Funda and Irisli, Sevil and Salek, Spencer N. and Senturk, Ozan S. and Went, Michael J. (1993) Coordination of copper and silver by [co2(mu-c2(ch2sch2ch2)2s)(co)6]. Journal of Organometallic Chemistry, 453 (2). C30-C31. ISSN 0022-328X. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitution.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Biosciences
Depositing User: R.F. Xu
Date Deposited: 15 Jul 2009 10:16
Last Modified: 02 May 2014 13:41
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