Rice, Craig R., Wallis, John D. (1993) Trans Deformation Of A Carbon Carbon Triple Bond In Response To Incipient Nucleophilic-Attack - The X-Ray Crystal-Structure Of Ethyl 3-(2-Nitrophenyl)Propynoate At 150 K. Journal of the Chemical Society-Chemical Communications, (6). pp. 572-574. ISSN 0022-4936. (doi:10.1039/C39930000572) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:20620)
The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
Official URL: http://dx.doi.org/10.1039/C39930000572 |
Abstract
In the title compound 1 the electron-deficient alkyne bond shows a pronounced trans distortion in response to an adjacent electron rich nitro O atom, suggesting that the more favourable reaction coordinate for addition of nucleophiles to activated alkynes involves trans rather than cis addition.
Item Type: | Article |
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DOI/Identification number: | 10.1039/C39930000572 |
Subjects: | Q Science > QD Chemistry |
Divisions: | Divisions > Division of Natural Sciences > Medway School of Pharmacy |
Depositing User: | E.C. Henry-Duru |
Date Deposited: | 04 Oct 2009 18:03 UTC |
Last Modified: | 16 Nov 2021 09:58 UTC |
Resource URI: | https://kar.kent.ac.uk/id/eprint/20620 (The current URI for this page, for reference purposes) |
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