Short Interactions Between Heterocyclic Sulfur-Atoms and Thiocarbonyl Sulfur or Carbonyl Oxygen-Atoms

Hudson, R.F. and Wallis, John D. and Hansell, D.P. (1994) Short Interactions Between Heterocyclic Sulfur-Atoms and Thiocarbonyl Sulfur or Carbonyl Oxygen-Atoms. Heterocycles, 37 (3). pp. 1933-1950. ISSN 0385-5414. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Abstract

Short intramolecular S---S=C contacts in N-(2-thiazolylidene)-benzenecarbothioamides (11 and 12), 0.60angstrom less than the corresponding separation predicted by Van der Waals radii, are accounted for by Coulombic interactions and 3d orbital participation as a result of electron delocalisation within each molecule. Similar considerations apply to S---O=C contacts, however short S---S intermolecular interactions between sulfides are due to the asymmetric electron distribution about the bonded sulfide atoms.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Engineering and Digital Arts
Depositing User: P. Ogbuji
Date Deposited: 25 Jun 2009 13:03
Last Modified: 25 Jun 2014 11:28
Resource URI: https://kar.kent.ac.uk/id/eprint/20261 (The current URI for this page, for reference purposes)
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