Hague, D.N. and Moreton, A.D. (1994) Protonation Sequence of Linear Aliphatic Polyamines by C-13 NMR-Spectroscopy. Journal of the Chemical Society-Perkin Transactions 2 (2). pp. 265-270. ISSN 0300-9580. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)
The C-13 NMR spectra are reported as a function of pH for 4,7-diazadecane-1,10-diamine, 4,8-diazaundecane-1,11-diamine and 3,6,9-triazaundecane-1,11-diamine. The previously reported amine shift parameters pi and pi(+) are used to determine the protonation sites in the partially protonated intermediate forms of these and a further five polyamines whose C-13-pH profiles have been published. The use of this simple method for determining protonation sequences is examined critically.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Engineering and Digital Arts|
|Depositing User:||P. Ogbuji|
|Date Deposited:||26 Jun 2009 07:46|
|Last Modified:||13 Jun 2012 08:12|
|Resource URI:||https://kar.kent.ac.uk/id/eprint/20240 (The current URI for this page, for reference purposes)|