Structural Role of Zirconium in SIO2-ZRO2 GELS - Evidence from 0-17 NMR

Dirken, Peter J. and Dupree, Ray and Smith, Mark E. (1995) Structural Role of Zirconium in SIO2-ZRO2 GELS - Evidence from 0-17 NMR. Journal of Materials Chemistry, 5 (8). pp. 1261-1263. ISSN 0959-9428. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Official URL
http://dx.doi.org/10.1039/JM9950501261

Abstract

O-17 MAS NMR has been applied to SiO2-ZrO2 mixed alkoxide derived gels. It demonstrates unambiguously that Zr-O-Si bonds are formed during gelling and that there is almost complete solid solution of Zr into the SiO2 network. Preliminary results on a ternary SiO2-TiO2-ZrO2 gel clearly indicate that Ti and Zr have different chemical behaviour in these systems.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Engineering and Digital Arts
Depositing User: P. Ogbuji
Date Deposited: 03 Jun 2009 10:42
Last Modified: 09 Jun 2014 10:31
Resource URI: https://kar.kent.ac.uk/id/eprint/19814 (The current URI for this page, for reference purposes)
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