Mapping of the Functional Active-SITE of Baeyer-Villigerases by Substrate Engineering

Kelly, David R. and Knowles, Christopher J. and Mahdi, Jasem G. and Taylor, Ian N. and Wright, Michael A.E. (1995) Mapping of the Functional Active-SITE of Baeyer-Villigerases by Substrate Engineering. Journal of the Chemical Society-Chemical Communications (7). pp. 729-730. ISSN 0022-4936. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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Abstract

An active sits model for enzyme catalysed Baeyer-Villiger reactions is proposed and validated by transformation of the tricyclic ketone 6; Baeyer-Villiger reactions (and Baeyer-Villigerases) are classified by the stereochemistry of the hydroxyperoxide intermediate.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Biosciences
Depositing User: P. Ogbuji
Date Deposited: 28 May 2009 18:18
Last Modified: 28 May 2014 08:38
Resource URI: https://kar.kent.ac.uk/id/eprint/19642 (The current URI for this page, for reference purposes)
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