Stereochemical congruence of Baeyer-Villigerases

Kelly, David R. and Knowles, Christopher J. and Mahdi, Jasem G. and Wright, Michael A.E. and Taylor, Ian N. and Roberts, Stanley M. and Wan, Peter W. H. and Grogan, Gideon and PedragosaMoreau, Sandrine and Willetts, Andrew J. (1996) Stereochemical congruence of Baeyer-Villigerases. Chemical Communications (20). pp. 2333-2334. ISSN 1359-7345. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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The enantiomeric bicyclic ketones 1, 3 and the tricyclic ketone 5 undergo stereochemically congruent Baeyer-Villiger oxidations with CHMO from Acinetobacter sp,, CPMO from Pseudomonas sp, as well as 2,5-DKCMO, 3,6-DKCMO and MO2 from P, putida; in every case the tricyclic ketone 5 is transformed with > 96% ee, N-terminal sequences for the FAD/NADPH linked enzymes from Acinetobacter sp,, Pseudomonas sp, and a novel CHMO from R, coprophilus have high homology with each other but no homology with the FMN/NADH linked enzymes; 2,5-DKCMO and 3,6-DKCMO.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Biosciences
Depositing User: R.F. Xu
Date Deposited: 27 May 2009 13:55
Last Modified: 28 May 2014 08:36
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