Zinc(II) complexes of putative obligate tetrahedrally co-ordinating pro-ligands

Connor, Joseph A., Charlton, Michael, Cupertino, Domenico C., Lienke, Achim, McPartlin, Mary, Scowen, Ian J., Tasker, Peter A. (1996) Zinc(II) complexes of putative obligate tetrahedrally co-ordinating pro-ligands. Journal of the Chemical Society-Dalton Transactions, (13). pp. 2835-2838. ISSN 0300-9246. (doi:10.1039/DT9960002835) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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http://dx.doi.org/10.1039/DT9960002835

Abstract

An attempt to impose tetrahedral geometry on zinc(II) through use of bis(salicylideneamino)biphenyl pro-ligands has produced hydrolytically sensitive complexes. The single-crystal structures of [ZnL(EtOH)] [H(2)L = 6,6'-dimethyl-2,2'-bis(salicylideneamino)biphenyl][monoclinic, space group P2(1)/c, a = 11.654(2), b = 11.753(2), c = 18.878(3) Angstrom, beta = 98.97(2)degrees, Z = 4] and its pro-ligand H(2)L [monoclinic, space group I2/c, a = 13.911(2), b = 13.759(2), c = 12.015(2) Angstrom, beta = 94.836(10)degrees, Z = 4] have been determined. The co-ordination geometry at zinc is slightly distorted trigonal bipyramidal.

Item Type: Article
DOI/Identification number: 10.1039/DT9960002835
Subjects: Q Science
Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: M.A. Ziai
Date Deposited: 15 May 2009 00:40 UTC
Last Modified: 28 May 2019 13:57 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/18889 (The current URI for this page, for reference purposes)
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