Hageman, Hendrik J. (1998) Photoinitiators and photoinitiation, Part 14. N-substituted sulphamic esters of alpha-hydroxymethylbenzoin and alpha-hydroxymethylbenzoin ethers as multifunctional photo-initiators. Journal of Photochemistry and Photobiology a-Chemistry, 117 (3). pp. 235-238. ISSN 1010-6030. (doi:10.1016/S1010-6030(98)00324-4) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:17792)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1016/S1010-6030(98)00324-4 |
Abstract
Several new N-substituted sulphamic esters of alpha-hydroxymethylbenzoin and alpha-hydroxymethylbenzoin ethers have been synthesized. They are shown to release acids on irradiation, and hence to be capable of inducing the acid-catalyzed crosslinking of a melamine resin. They are also shown to photoinitiate the polymerization and crosslinking of acrylates, in all likelihood by the generation of reactive benzoyl and benzoylmethyl radicals, as concluded from a comparison with corresponding sulphonic esters of a-hydroxymethylbenzoin and its ethers.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/S1010-6030(98)00324-4 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | R.F. Xu |
| Date Deposited: | 26 Oct 2009 19:33 UTC |
| Last Modified: | 16 Nov 2021 09:55 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/17792 (The current URI for this page, for reference purposes) |
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