Benfield, Robert E., Filipponi, A., Morgante, N., Schmid, Gunter (1999) Structural characterisation of the giant organometallic platinum cluster Pt-309(phen*)(36)O-30 using EXAFS. Journal of Organometallic Chemistry, 573 (1-2). pp. 299-304. ISSN 0022-328X. (doi:10.1016/S0022-328X(98)00878-X) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:17071)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1016/S0022-328X(98)00878-X |
Abstract
The structure of the high-nuclearity organometallic platinum cluster material Pt-309(phen*)(36)O-30 has been investigated by X-ray absorption spectroscopy. Analysis of Pt L-3-edge EXAFS data, using platinum foil as a reference, shows that the platinum clusters have cubic close packed geometry. A slight contraction of the Pt-Pt bond length from the bulk was observed. XANES analysis shows that the platinum atoms in the clusters have a low mean oxidation state, very close to that in metallic platinum. (C) 1999 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/S0022-328X(98)00878-X |
| Uncontrolled keywords: | Platinum; Clusters; EXAFS; Lattice contraction; XANES |
| Subjects: |
T Technology > TP Chemical technology Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | M. Nasiriavanaki |
| Date Deposited: | 13 Jul 2009 07:04 UTC |
| Last Modified: | 05 Nov 2024 09:52 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/17071 (The current URI for this page, for reference purposes) |
- Export to:
- RefWorks
- EPrints3 XML
- BibTeX
- CSV
- Depositors only (login required):
Altmetric
Altmetric
