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Thermodynamic and kinetic analysis of isothermal microcalorimetric data: applications to consecutive reaction schemes

Gaisford, Simon, Hills, Andrew K., Beezer, Anthony E., Mitchell, John C. (1999) Thermodynamic and kinetic analysis of isothermal microcalorimetric data: applications to consecutive reaction schemes. Thermochimica Acta, 328 (1-2). pp. 39-45. ISSN 0040-6031. (doi:10.1016/S0040-6031(98)00622-4) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:16789)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://dx.doi.org/10.1016/S0040-6031(98)00622-4

Abstract

Recent developments have led to a general procedure that allows the analysis of isothermal microcalorimetric data to determine both kinetic and thermodynamic information. Such an analysis means that isothermal microcalorimetry is a powerful technique with which to gain information on a wide range of reactions. Previously, the method of analysis has, principally, been applied to simple, two-stare, solution phase reactions. It is the purpose of the data presented here to show how such an analysis may be applied to solution phase reactions that follow more complex, consecutive reaction pathways using, as a model and example, the acid catalyzed hydrolysis of potassium hydroxylamine trisulfonate.

Item Type: Article
DOI/Identification number: 10.1016/S0040-6031(98)00622-4
Additional information: Issue: 1-2
Uncontrolled keywords: microcalorimetric data; solution phase reactions; thermodynamic analysis
Subjects: Q Science
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: I.T. Ekpo
Date Deposited: 29 Jun 2011 07:47 UTC
Last Modified: 07 Jun 2019 10:22 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/16789 (The current URI for this page, for reference purposes)
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