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Structural change in D2O water as a function of temperature: the isochoric temperature derivative function for neutron diffraction

Dore, John C., Sufi, M.A.M., Bellissent-Funel, Marie-Claire (2000) Structural change in D2O water as a function of temperature: the isochoric temperature derivative function for neutron diffraction. Physical Chemistry Chemical Physics, 2 (8). pp. 1599-1602. ISSN 1463-9076. (doi:10.1039/a909322b) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:16396)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
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htt://dx.doi.org/10.1039/a909322b

Abstract

Neutron diffraction measurements have been made for liquid D2O water at four temperatures covering the normal and super-cooled phases. Pairs of temperatures have been chosen where the density is equivalent, either side of the density maximum. A temperature difference technique is used to extract the change in the structure factor as a function of temperature and this function is transformed to give the change in the composite spatial correlation function. It is shown that there is a systematic variation in the structure which extends over a range up to 10 Angstrom and above. The changes can be correlated with the network structure of low-density amorphous ice and these features emphasise the extended range of the hydrogen-bond connectivity in the liquid phase.

Item Type: Article
DOI/Identification number: 10.1039/a909322b
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User: P. Ogbuji
Date Deposited: 21 Mar 2009 00:13 UTC
Last Modified: 16 Nov 2021 09:54 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/16396 (The current URI for this page, for reference purposes)

University of Kent Author Information

Dore, John C..

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