Bell, Paul C. and Drameh, M. and Hanly, N. and Wallis, John D. (2000) Interaction between a dimethylamino group and an electron-deficient alkene in ethyl (E)-2-cyano-3-(8-dimethylamino-1-naphthyl)propenoate. Acta Crystallographica Section C-Crystal Structure Communications, 56 (6). pp. 670-671. ISSN 0108-2701. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)
The interaction between the peri substituents in the title compound, C18H18N2O2, measured at 150 K, represents an early stage in the addition reaction of an amino group to an electron-deficient alkene, and has an N ... Csp(2) separation of 2.531 (2) Angstrom; comparison with related structures indicates that the nitrile group activates an alkene to nucleophilic attack more than a coplanar carboxylic ester group.
|Subjects:||A General Works|
|Depositing User:||P. Ogbuji|
|Date Deposited:||24 Jun 2009 11:43|
|Last Modified:||17 Jun 2014 11:31|
|Resource URI:||https://kar.kent.ac.uk/id/eprint/16119 (The current URI for this page, for reference purposes)|