Dore, John C. and Webber, J. Beau W. and Strange, John H. and Farman, Hossein and Descamps, Marc and Carpentier, Laurent (2004) Phase transformations for cyclohexane in mesoporous silicas. Physica A: Statistical Mechanics and its Applications, 333 . pp. 10-16. ISSN 03784371. (doi:https://doi.org/10.1016/j.physa.2003.09.043) (Access to this publication is currently restricted. You may be able to access a copy if URLs are provided)
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Neutron diffraction (ND), nuclear magnetic resonance (NMR) and differential scanning calorimetry (DSC) studies have been used to study the structural features of cyclohexane in the confined geometry of several mesoporous silicas with a pore size in the range 25-500 Angstrom. The results show a consistent depression of the nucleation temperature that is inversely proportional to the pore size and appear to be related to the orientational correlations in the various phases. In the extreme case of MCM silicas, there is evidence that nucleation is completely suppressed.
|Uncontrolled keywords:||confined geometry; neutron diffraction; cryoporometry|
|Subjects:||Q Science > QC Physics|
|Divisions:||Faculties > Sciences > School of Physical Sciences > Functional Materials Group|
|Depositing User:||J.B.W. Webber|
|Date Deposited:||29 May 2009 07:22 UTC|
|Last Modified:||12 Jan 2017 13:47 UTC|
|Resource URI:||https://kar.kent.ac.uk/id/eprint/13461 (The current URI for this page, for reference purposes)|