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Phase relations for water and ice in confined geometry

Dore, John C. and Webber, J. Beau W. and Behrens, Peter and Haggenmuller, C and Montague, C. (2002) Phase relations for water and ice in confined geometry. In: Brazhkin, VV and Buldyrev, SV and Ryzhov, VN and Stanley, HE, eds. New kinds of phase transitions: Transformations in disordered substances. SPRINGER, PO BOX 17, 3300 AA DORDRECHT, NETHERLANDS, pp. 469-480. ISBN 1-4020-0825-2. (doi:10.1007/978-94-010-0595-1_35) (KAR id:13455)

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https://doi.org/10.1007/978-94-010-0595-1_35

Abstract

A brief survey is given of the structural characteristics of water at low temperatures in the normal and super-cooled states using neutron diffraction. Similar studies axe presented for D2O water in mesoporous sol-gel silicas showing the depression of the nucleation temperature, the effects of fractional filling and the formation of cubic ice I-c in the pores. Preliminary data is also presented for both neutron and x-ray diffraction studies of water in the ordered MCM41 silica, showing the deep super-cooling and the reversible phase transformation between water and cubic ice. The importance of hydrogen-bonded networks and the development of long-range correlations axe used to provide an explanation of the observations. Further work is in progress.

Item Type: Book section
DOI/Identification number: 10.1007/978-94-010-0595-1_35
Additional information: NATO Advanced Research Workshop on New Kinds of Phase Transitions - Transformations in Disordered Substances, RUSSIA, MAY 24-28, 2001
Subjects: Q Science > QC Physics
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User: J.B.W. Webber
Date Deposited: 11 Mar 2009 22:56 UTC
Last Modified: 09 Mar 2023 11:29 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/13455 (The current URI for this page, for reference purposes)
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