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Complex magnetic ordering behavior in the frustrated perovskite Ba2MnMoO6

Coomer, Fiona C., Mutch, Heather M., Mustonen, Otto, Pughe, Charlotte, Cussen, Serena A., Ramos, Silvia, Hillier, Adrian D., Cussen, Edmund J. (2023) Complex magnetic ordering behavior in the frustrated perovskite Ba2MnMoO6. APL Materials, 11 (5). Article Number 051111. ISSN 2166-532X. (doi:10.1063/5.0144719) (KAR id:101331)

Abstract

New and exotic ground states of magnetic materials are highly sought after and are extensively studied for the insights they provide into the thermodynamics of disorder and fundamental magnetic interactions. By controlling the crystal structure of an appropriate magnetic lattice, it is possible to cause the strong magnetic exchange interactions to sum to zero and so be frustrated. Due to the presence of this frustration, the lowest energy configuration that results may be crucially dependent on the tiniest of energy differences between a multitude of states that have (almost) the same energy. The keen interest in these materials arises from the fact that these finely balanced systems offer a way of probing classical or quantum mechanical interactions that are of fundamental importance but are too weak to be observed in non-frustrated systems. Here, we combine local and crystallographic probes of the cation-ordered double perovskite Ba2MnMoO6 that contains a face-centered cubic lattice of S = 5/2 Mn2+ cations. Neutron diffraction measurements below 9.27(7) K indicate that a fourfold degenerate non-collinear antiferromagnetic state exists with almost complete ordering of the Mn2+ spins. Muon spin relaxation measurements provide a local probe of the magnetic fields inside this material over the t1/2 = 2.2 µs lifetime of a muon, indicating a slightly lower Néel transition temperature of 7.9(1) K. The dc susceptibility data do not show the loss of magnetization that should accompany the onset of the antiferromagnetic order; they indicate that a strongly antiferromagnetically coupled paramagnetic state [θ = −73(3) K] persists down to 4 K, at which temperature a weak transition occurs. The behavior of this material differs considerably from the closely related compositions Ba2MnMO6 (M = W, Te), which show collinear ordering arrangements and well defined antiferromagnetic transitions in the bulk susceptibility. This suggests that the Mo6+ cation leads to a fine balance between the nearest and next-nearest neighbor superexchange in these frustrated double perovskite structures.

Item Type: Article
DOI/Identification number: 10.1063/5.0144719
Additional information: For the purpose of open access, the author(s) has applied a Creative Commons Attribution (CC BY) licence to any Author Accepted Manuscript version arising.
Uncontrolled keywords: General Engineering, General Materials Science
Subjects: Q Science > QC Physics
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Funders: Engineering and Physical Sciences Research Council (https://ror.org/0439y7842)
Leverhulme Trust (https://ror.org/012mzw131)
SWORD Depositor: JISC Publications Router
Depositing User: JISC Publications Router
Date Deposited: 19 May 2023 13:13 UTC
Last Modified: 12 Dec 2023 12:09 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/101331 (The current URI for this page, for reference purposes)

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