Punzo, F. and Cowley, A.R. and Watkin, David J. and Simone, M.L. and Edwards, Alison A. and Tranter, George E. and Fleet, George W.J. (2006) Pentafluorophenyl (3R,4R,5R)-5-{[(3R,4R,5R)-5-azidomethyl-3,4-dimethoxy-2,3,4,5-tetrahydrofuran-3-carbonylamino]methyl}-3,4-dimethoxy-2,3,4,5-tetrahydrofuran-3-carboxylate. Acta Crystallographica, E62 . 0473-0475. ISSN 1600-5368 .
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| Official URL http://dx.doi.org/10.1107/S1600536805043205 |
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Abstract
The crystal structure of the title compound, C22H25F5N4O9, an important intermediate in the synthesis of novel biopolymers containing branched carbon chains, establishes the relative stereochemistry at all six chiral centres of the dipeptide. The structure may indicate a predisposition to the organization of secondary structure by novel dipeptide isosteres. An intermolecular hydrogen bond between the NH group and one of the N atoms of the azide group contributes to the stabilization of the packing.
| Item Type: | Article |
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| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | Faculties > Science Technology and Medical Studies > Medway School of Pharmacy |
| Depositing User: | Alison Edwards |
| Date Deposited: | 03 Sep 2008 22:08 |
| Last Modified: | 28 May 2012 10:46 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/4892 (The current URI for this page, for reference purposes) |
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