Pentafluorophenyl (3R,4R,5R)-5-{[(3R,4R,5R)-5-azidomethyl-3,4-dimethoxy-2,3,4,5-tetrahydrofuran-3-carbonylamino]methyl}-3,4-dimethoxy-2,3,4,5-tetrahydrofuran-3-carboxylate

Punzo, Francesco and Cowley, Andrew R. and Watkin, David J. and Simone, Michela L. and Edwards, Alison A. and Tranter, George E. and Fleet, George W.J. (2006) Pentafluorophenyl (3R,4R,5R)-5-{[(3R,4R,5R)-5-azidomethyl-3,4-dimethoxy-2,3,4,5-tetrahydrofuran-3-carbonylamino]methyl}-3,4-dimethoxy-2,3,4,5-tetrahydrofuran-3-carboxylate. Acta Crystallographica, E62 . 0473-0475. ISSN 1600-5368 . (Access to this publication is restricted)

PDF
Restricted to Repository staff only
Contact us about this Publication Download (221kB)
[img]
Official URL
http://dx.doi.org/10.1107/S1600536805043205

Abstract

The crystal structure of the title compound, C22H25F5N4O9, an important intermediate in the synthesis of novel biopolymers containing branched carbon chains, establishes the relative stereochemistry at all six chiral centres of the dipeptide. The structure may indicate a predisposition to the organization of secondary structure by novel dipeptide isosteres. An intermolecular hydrogen bond between the NH group and one of the N atoms of the azide group contributes to the stabilization of the packing.

Item Type: Article
Subjects: Q Science
Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > Medway School of Pharmacy
Depositing User: Alison Edwards
Date Deposited: 03 Sep 2008 22:08
Last Modified: 30 Jun 2014 11:40
Resource URI: http://kar.kent.ac.uk/id/eprint/4892 (The current URI for this page, for reference purposes)
  • Depositors only (login required):

Downloads

Downloads per month over past year