Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene

Berko, Aaron and Horton, Peter N. and Hursthouse, Michael B. and Packer, Robert J. and Went, Michael J. (2005) Synthesis of an alkene functionalised thiamacrocycle, 2,11-divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene. Inorganic Chemistry Communications, 8 (5). pp. 488-490. ISSN 1387-7003. (Full text available)

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http://dx.doi.org/10.1016/j.inoche.2005.03.003

Abstract

Base-catalysed rearrangement of 1,4,7-trithiacycloundec-9-yne affords 2,11-Divinyl-1,4,7,10,13,16-hexathiacyclooctadeca-2,11-diene characterised by NMR spectroscopy and X-ray crystallography. The 18-membered macrocycle has six of the 12 C-S bonds in gauche configurations.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences > Functional Materials Group
Depositing User: Michael J Went
Date Deposited: 30 Aug 2008 21:15
Last Modified: 28 Apr 2014 09:01
Resource URI: http://kar.kent.ac.uk/id/eprint/3765 (The current URI for this page, for reference purposes)
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