Rossi, N.A.A. and Anderson, R.M. and Jones, R.G. and Holder, S.J. (2004) Synthesis of poly(styrene-block-methylphenylsilane-block-styrene) via TEMPO-mediated controlled free radical polymerisation. Polymer International, 53 (4). pp. 465-471. ISSN 0959-8103.
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Abstract
ABA block copolymers of styrene and methylphenylsilane were synthesized using a methodology based on 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-mediated controlled free radical polymerisation. Samples of alpha,omega-dihalo(polymethylphenysilane) were reacted with a hydroxyl derivative of TEMPO to give suitable macroinitiators for the controlled ('living') free radical polymerisation of styrene. The polymerisation of styrene was carried out in bulk at 130degreesC. Block copolymers were characterised using size exclusion chromatography and H-1 and C-13 NMR spectroscopy. (C) 2004 Society of Chemical Industry.
| Item Type: | Article |
|---|---|
| Additional information: | 37 JOHN WILEY & SONS LTD |
| Uncontrolled keywords: | block copolymers; TEMPO; polymethylphenylsilane; polystyrene; controlled radical polymerisation; macroinitiator METHACRYLATE) BLOCK-COPOLYMERS; POLYSILANE HIGH POLYMERS; CROSS-LINKED MICELLES; TRIBLOCK COPOLYMERS; COUPLING REACTION; POLYSTYRENE; POLY(METHYLPHENYLSILYLENE); ENCAPSULATION; GENERATION; TRANSPORT |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Physical Sciences > Functional Materials Group |
| Depositing User: | Simon Holder |
| Date Deposited: | 03 Sep 2008 15:13 |
| Last Modified: | 14 Jan 2010 14:07 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/2566 (The current URI for this page, for reference purposes) |
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