The Direct Correlation-Function for A Fluid Of Hard Molecules

Rickayzen, Gerald (1992) The Direct Correlation-Function for A Fluid Of Hard Molecules. In: Journal of Molecular Liquids. British Radiofrequency Spectroscopy, 54. Elsevier Science BV, PO Box 211, 1000 AE Amsterdam, Netherlands, Amsterdam, Netherlands pp. 311-320. (The full text of this publication is not available from this repository)

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Abstract

A new approximation is proposed for the direct correlation function of a homogeneous fluid of hard molecules. As in scaled particle theory [5], and in the scaled field particle theory of Rosenfeld [6] the direct correlation function is expressed as a linear combination of four basic functions representing different geometrical features of two molecules. In the new approximation the weights of the basic functions are determined in such a way that the approximate correlation functions satisfy four equations which are also satisfied by the Percus-Yevick (PY) solutions. When the method is applied to the hard sphere fluid with an appropriate choice of basic functions, it yields the PY solution for the correlation function.

Item Type: Conference or workshop item (Paper)
Additional information: issue number: 4
Subjects: Q Science > QD Chemistry
Q Science > QC Physics
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences
Depositing User: M. Nasiriavanaki
Date Deposited: 20 Aug 2009 07:43
Last Modified: 04 Jun 2014 12:34
Resource URI: http://kar.kent.ac.uk/id/eprint/22415 (The current URI for this page, for reference purposes)
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