Structure and Mechanism in the Cyclopolymerization of Diallylsilanes

Jones, R.G. and Cragg, R.H. and Swain, A.C. (1992) Structure and Mechanism in the Cyclopolymerization of Diallylsilanes. European Polymer Journal, 28 (6). pp. 651-655. ISSN 0014-3057. (The full text of this publication is not available from this repository)

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Abstract

C-13- and Si-29-NMR spectroscopy are applied to the structural determination of the low molecular weight cyclopolymer formed from diallylmethylphenylsilane by a cationic mechanism. The ease of transfer to monomer, characteristic of the cyclopolymerization of diallylsilanes, is attributed to the ready formation of a resonance-stabilized chain-end structure.

Item Type: Article
Subjects: Q Science
Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences
Depositing User: M. Nasiriavanaki
Date Deposited: 04 Sep 2009 08:36
Last Modified: 04 Sep 2009 08:36
Resource URI: http://kar.kent.ac.uk/id/eprint/22318 (The current URI for this page, for reference purposes)
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