Demirhan, F. and Irisli, S. and Salek, S.N. and Senturk, O.S. and Went, M.J. and Jeffery, J.C. (1993) Coordination of copper and silver by [co2(mu-c2(ch2sch2ch2)2s)(co)6]. Journal of Organometallic Chemistry, 453 (2). C30-C31. ISSN 0022-328X.
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Abstract
The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitution.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Biosciences |
| Depositing User: | R.F. Xu |
| Date Deposited: | 15 Jul 2009 10:16 |
| Last Modified: | 15 Jul 2009 10:16 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/20871 (The current URI for this page, for reference purposes) |
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