Coordination of copper and silver by [co2(mu-c2(ch2sch2ch2)2s)(co)6]

Demirhan, Funda and Irisli, Sevil and Salek, Spencer N. and Senturk, Ozan S. and Went, Michael J. (1993) Coordination of copper and silver by [co2(mu-c2(ch2sch2ch2)2s)(co)6]. Journal of Organometallic Chemistry, 453 (2). C30-C31. ISSN 0022-328X. (The full text of this publication is not available from this repository)

The full text of this publication is not available from this repository. (Contact us about this Publication)
Official URL
http://dx.doi.org/10.1016/0022-328X(93)83134-H

Abstract

The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitution.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Biosciences
Depositing User: R.F. Xu
Date Deposited: 15 Jul 2009 10:16
Last Modified: 02 May 2014 13:41
Resource URI: http://kar.kent.ac.uk/id/eprint/20871 (The current URI for this page, for reference purposes)
  • Depositors only (login required):