Davidson, R.S. and Liu, J. (1993) Preparation, Characterization and photochemistry of 4,4diacetamidostilbene and its beta-cyclodextrin inclusion complex. Journal of Photochemistry and Photobiology a-Chemistry, 76 (1-2). pp. 121-126. ISSN 1010-6030.
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The inclusion complex of trans-4,4'-diacetamidostilbene (1, DAST) with beta-cyclodextrin (2, DAST-CD) was prepared. The formation of the complex and its photochemical behaviour were investigated using a range of physical methods (H-1 and C-13 nuclear magnetic resonance (NMR) spectroscopy, fluorescence and absorption spectroscopy). The results indicate that a stable 1:1 inclusion complex is produced in the solid state and in methanol and dimethylsulphoxide. The guest molecule is completely encapsulated in the beta-cyclodextrin cavity. No difference in stability was observed between DAST and DAST-CD when the samples were irradiated by UV light in methanol. The photolysis products in dimethylsulphoxide were studied using H-1 NMR spectroscopy; the results indicate that the photolysis products are cis-DAST and 4,4'-diacetamidophenanthrene for DAST-CD, but cis-DAST only for DAST.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Biosciences|
|Depositing User:||R.F. Xu|
|Date Deposited:||18 Jul 2009 09:12|
|Last Modified:||18 Jul 2009 09:12|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/20866 (The current URI for this page, for reference purposes)|
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