Bosch, P. and Delmonte, F. and Mateo, J.L. and Davidson, R.S. (1993) New cleavage photoinitiators for radical polymerization - synthesis and photochemical study of dibromo derivatives of dibenzoylmethane. Journal of Photochemistry and Photobiology a-Chemistry, 73 (3). pp. 197-204. ISSN 1010-6030.
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Abstract
Dibromo derivatives of p-substituted dibenzoylmethanes have been prepared. Elucidation of the fragmentation mechanism on continuous irradiation has shown that homolytic fragmentation of the C-Br bond is produced. The quantum yields for chromophore destruction are high and are indicative of high rates of radical production. A photocalorimetric and real time IR (RTIR) study of radical polymerization of acrylic monomers has shown that these compounds are excellent photoinitiators, the bromine radical being the initiating species.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Biosciences |
| Depositing User: | R.F. Xu |
| Date Deposited: | 09 Oct 2009 16:28 |
| Last Modified: | 09 Oct 2009 16:28 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/20806 (The current URI for this page, for reference purposes) |
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