Rice, C.R. and Wallis, J.D. (1993) Trans Deformation Of A Carbon Carbon Triple Bond In Response To Incipient Nucleophilic-Attack - The X-Ray Crystal-Structure Of Ethyl 3-(2-Nitrophenyl)Propynoate At 150 K. Journal of the Chemical Society-Chemical Communications (6). pp. 572-574. ISSN 0022-4936.
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In the title compound 1 the electron-deficient alkyne bond shows a pronounced trans distortion in response to an adjacent electron rich nitro O atom, suggesting that the more favourable reaction coordinate for addition of nucleophiles to activated alkynes involves trans rather than cis addition.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > Medway School of Pharmacy|
|Depositing User:||E.C. Henry-Duru|
|Date Deposited:||04 Oct 2009 18:03|
|Last Modified:||04 Oct 2009 18:03|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/20620 (The current URI for this page, for reference purposes)|
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