Trans Deformation Of A Carbon Carbon Triple Bond In Response To Incipient Nucleophilic-Attack - The X-Ray Crystal-Structure Of Ethyl 3-(2-Nitrophenyl)Propynoate At 150 K

Rice, Craig R. and Wallis, John D. (1993) Trans Deformation Of A Carbon Carbon Triple Bond In Response To Incipient Nucleophilic-Attack - The X-Ray Crystal-Structure Of Ethyl 3-(2-Nitrophenyl)Propynoate At 150 K. Journal of the Chemical Society-Chemical Communications (6). pp. 572-574. ISSN 0022-4936. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1039/C39930000572

Abstract

In the title compound 1 the electron-deficient alkyne bond shows a pronounced trans distortion in response to an adjacent electron rich nitro O atom, suggesting that the more favourable reaction coordinate for addition of nucleophiles to activated alkynes involves trans rather than cis addition.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > Medway School of Pharmacy
Depositing User: E.C. Henry-Duru
Date Deposited: 04 Oct 2009 18:03
Last Modified: 25 Jun 2014 11:28
Resource URI: http://kar.kent.ac.uk/id/eprint/20620 (The current URI for this page, for reference purposes)
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