Short Interactions Between Heterocyclic Sulfur-Atoms and Thiocarbonyl Sulfur or Carbonyl Oxygen-Atoms

Hudson, R.F. and Wallis, J.D. and Hansell, D.P. (1994) Short Interactions Between Heterocyclic Sulfur-Atoms and Thiocarbonyl Sulfur or Carbonyl Oxygen-Atoms. Heterocycles, 37 (3). pp. 1933-1950. ISSN 0385-5414. (The full text of this publication is not available from this repository)

The full text of this publication is not available from this repository. (Contact us about this Publication)

Abstract

Short intramolecular S---S=C contacts in N-(2-thiazolylidene)-benzenecarbothioamides (11 and 12), 0.60angstrom less than the corresponding separation predicted by Van der Waals radii, are accounted for by Coulombic interactions and 3d orbital participation as a result of electron delocalisation within each molecule. Similar considerations apply to S---O=C contacts, however short S---S intermolecular interactions between sulfides are due to the asymmetric electron distribution about the bonded sulfide atoms.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Engineering and Digital Arts
Depositing User: P. Ogbuji
Date Deposited: 25 Jun 2009 13:03
Last Modified: 13 Jun 2012 09:36
Resource URI: http://kar.kent.ac.uk/id/eprint/20261 (The current URI for this page, for reference purposes)
  • Depositors only (login required):