Hague, D.N. and White, A.R. (1994) Kinetics of Ternary Complex- Formation Between Cobalt (II)sPECIES AND 5-Nitrosalicylic Acid - the Effect of Charge. Journal of the Chemical Society-Dalton Transactions (24). pp. 3645-3650. ISSN 0300-9246.
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The temperature-jump relaxation method has been used to measure rate constants and activation parameters for the formation and dissociation of a 1:1 complex between cobalt(II) and 5-nitrosalicylate(2-) (nsa(2-)), and of ternary complexes between nsa(2-) and cobalt(II)-nitrilotriacetate,-ethylenediamine N,N-diacetate,-ethylenediamine-N,N'-diacetate, and -triethylenetetramine; also rate constants for the formation and dissociation of ternary complexes between nsa and cobalt(II)-polytriphosphate,-iminodiacetate and -diethylenetriamine. Independently determined equilibrium constants are reported for [Co(nsa)] and for the ternary complexes involving polytriphosphate, nitrilotriacetate, ethylenediamine-N,N-diacetate and N,N'-diacetate. The rate parameters are compared with those for the corresponding nickel(II) reactions and for the corresponding reactions of both metals with the neutral ligand N,N-dimethyl (p-pyridin-2-ylazo)aniline. The results for nsa re only partly explicable in terms of the Fuoss equation.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Engineering and Digital Arts|
|Depositing User:||P. Ogbuji|
|Date Deposited:||26 Jun 2009 07:39|
|Last Modified:||13 Jun 2012 08:12|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/20241 (The current URI for this page, for reference purposes)|
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