Twyman, L.J and Beezer, A.E and Mitchell, J.C (1994) An Approach for the Rapid Synthesis of Moderately sized Dendritic Macromolecules. Journal of the Chemical Society-Perkin Transactions 1 (4). pp. 407-411. ISSN 0300-922X.
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A general method for the synthesis of a dendrimeric series with homologous terminal groups is described. FABMS measurements confirm the molecular mass of the reported dendrimers. The result of size exclusion chromatographic (SEC) analysis correlates well with the relative molecular mass (RMM) of the early members of the series. However, deviations in measurements of molecular mass by SEC and FABMS begin to appear for larger members of the series, suggesting a more spherical conformation when the terminal group exceeds propyl.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Biosciences|
|Depositing User:||P. Ogbuji|
|Date Deposited:||10 Jun 2009 07:26|
|Last Modified:||10 Jun 2009 07:26|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/20081 (The current URI for this page, for reference purposes)|
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