Structural Characterization of the Aluminum Sites in Kyanite by AL-27 mAGIC-Angle-Spinging Centerband, Satellite Transition and Double-Rotation NMR

Smith, Mark E. and Jaeger, C. and Schoenhofer, R. and Steuernagel, S. (1994) Structural Characterization of the Aluminum Sites in Kyanite by AL-27 mAGIC-Angle-Spinging Centerband, Satellite Transition and Double-Rotation NMR. Chemical Physics Letters, 219 (1-2). pp. 75-80. ISSN 0009-2614. (The full text of this publication is not available from this repository)

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Abstract

Al-27 solid state NMR allows the isotropic chemical shift and quadrupolar interaction parameters for the four crystallographically inequivalent AlO6 sites in kyanite, a polymorph of Al2SiO5, to be deduced. Magic angle spinning at two fields (11.7 and 17.55 T), satellite transitions and double rotation accurately constrain the Al-27 NMR interactions. The advantages of the differing techniques are discussed.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Engineering and Digital Arts
Depositing User: P. Ogbuji
Date Deposited: 18 Jun 2009 12:09
Last Modified: 09 Jun 2014 10:59
Resource URI: http://kar.kent.ac.uk/id/eprint/20048 (The current URI for this page, for reference purposes)
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