Short intermolecular s...s contacts in a reaction-product from the cyclic sulfate ester of dimethyl l-tartrate and 2-thioxo-1,3-dithiole-4,5-dithiolate

Ozturk, Turan and Povey, David C. and Wallis, John D. (1994) Short intermolecular s...s contacts in a reaction-product from the cyclic sulfate ester of dimethyl l-tartrate and 2-thioxo-1,3-dithiole-4,5-dithiolate. Tetrahedron, 50 (38). pp. 11205-11212. ISSN 0040-4020. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1016/S0040-4020(01)89422-9

Abstract

Cyclic sulfate ester 6 reacts readily with dithiolate 4 to give meso and dl cyclic products 8 and 9. The crystal structure of 9 shows two short S...S intermolecular interactions (< 3.4 Angstrom) between trithiocarbonate groups, due to cooperative polarisations and the highly asymmetric shape of the bonded S atom. The latter effect is mainly responsible for the 'short' S...S contacts in ET's radical cation salts. In contrast to similar systems, the sp(3) C atoms of the six-membered ring in 9 are displaced to the same side of the dithiole plane.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Biosciences
Depositing User: O.O. Odanye
Date Deposited: 05 Jul 2009 19:25
Last Modified: 25 Jun 2014 11:31
Resource URI: http://kar.kent.ac.uk/id/eprint/19931 (The current URI for this page, for reference purposes)
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