NMR Investment of the Structure of Aluminum-Containing Nitrogen Melilite(M'(SS))

Chee, Kok Sing and Cheng, Yi-Bing and Smith, Mark E. (1995) NMR Investment of the Structure of Aluminum-Containing Nitrogen Melilite(M'(SS)). Chemistry of Materials, 7 (5). pp. 982-988. ISSN 0897-4756. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1021/cm00053a026

Abstract

Replacement of silicon and nitrogen by aluminum and oxygen, respectively, in yttrium N-melilite (Y2Si3O3N4) forms an extensive solid solution M'(ss). M'(ss) samples formed in the yttrium system are often phase mixtures. Si-29 and Al-27 magic-angle spinning MMR spectra can consequently be complex, but combined with X-ray diffraction, resonances associated with M'(ss) can be identified and have elucidated possible atomic arrangements in M'(ss). The proposed yttrium M'(ss) structure based on NMR results consists of AlO4 and SiO2N2 coordinations only, with aluminum occupying the MgO4 sites in the analogous akermanite structure and accounts far the apparent limit of aluminum solubility in N-melilite.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Biosciences
Depositing User: P. Ogbuji
Date Deposited: 05 Jun 2009 18:57
Last Modified: 09 Jun 2014 10:31
Resource URI: http://kar.kent.ac.uk/id/eprint/19756 (The current URI for this page, for reference purposes)
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