Baxter, P.N.W. and Connor, J.A. (1995) Solvatochomsim in Sbstituted 2,2' -Bipyridintetracarbonyl-Metal Complexes of Chromium,Molybdenum and Tugsten. Journal of Organometallic Chemistry, 486 (1-2). pp. 115-121. ISSN 0022-328X.
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| Official URL http://dx.doi.org/10.1016/0022-328X(94)05058-J |
Abstract
The influence of various solvents on the electronic absorption spectra in the visible region of complexes of the general type [M(CO)(4)(n,n'-X(2)-bipy)] (M = Cr, Mo, W; n = 3, 4, 5, 6; X = CH3, CN, CO2CH3; bipy = 2,2'-bipyridine) has been measured. Molar absorption coefficients are reported. Attempts to correlate this information with the solvent polarity parameter proposed by Manuta and Lees indicate that the effects of geometric distortion in the substrate complex preclude a simple explanation of the observations in terms of a single parameter.
| Item Type: | Article |
|---|---|
| Uncontrolled keywords: | CHROMIUM, MOLYBDENUM; TUNGSTEN; SOLVATOCHROMISM; BIPYRIDINE; CARBONYL |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Engineering and Digital Arts |
| Depositing User: | P. Ogbuji |
| Date Deposited: | 08 Jun 2009 15:15 |
| Last Modified: | 08 May 2012 12:41 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/19695 (The current URI for this page, for reference purposes) |
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