Synthesis Of A Chiral Monosubstituted Derivative Of Bis(Ethylenedithio)Tetrathiafulvalene - Reaction Of The Cyclic Sulfate Ester Of R,R-1,4-Difluorobutane-2,3-Diol With 2-Thioxo-1,3-Dithiole-4,5-Dithiolate

Ozturk, T. and Rice, C.R and Wallis, J.D (1995) Synthesis Of A Chiral Monosubstituted Derivative Of Bis(Ethylenedithio)Tetrathiafulvalene - Reaction Of The Cyclic Sulfate Ester Of R,R-1,4-Difluorobutane-2,3-Diol With 2-Thioxo-1,3-Dithiole-4,5-Dithiolate. Journal of Materials Chemistry, 5 (10). pp. 1553-1556. ISSN 0959-9428. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1039/jm9950501553

Abstract

2-Thioxo-1,3-dithiole-4 5-dithiolate reacts stereospecifically with the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol by two nucleophilic attacks, ring opening of the cyclic sulfate ester at carbon and displacement of the nearer fluorine atom, to form a derivative of the 1,3-dithiolo[4,5-b]-1,4-dithiin ring system. This product is converted in two steps into an analogue of bis(ethylenedithio)tetrathiafulvalene with a 2-fluoro-1-hydroxyethyl side-chain, a new substrate for the preparation of electroactive materials.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Biosciences
Depositing User: O.O. Odanye
Date Deposited: 01 Jun 2009 19:56
Last Modified: 01 Jun 2009 19:56
Resource URI: http://kar.kent.ac.uk/id/eprint/19431 (The current URI for this page, for reference purposes)
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