Kelly, D.R. and Knowles, C.J. and Mahdi, J.G. and Wright, M.A. and Taylor, I.N. and Roberts, S.M. and Wan, P.W.H. and Grogan, G. and PedragosaMoreau, S. and Willetts, A.J. (1996) Stereochemical congruence of Baeyer-Villigerases. Chemical Communications (20). pp. 2333-2334. ISSN 1359-7345.
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The enantiomeric bicyclic ketones 1, 3 and the tricyclic ketone 5 undergo stereochemically congruent Baeyer-Villiger oxidations with CHMO from Acinetobacter sp,, CPMO from Pseudomonas sp, as well as 2,5-DKCMO, 3,6-DKCMO and MO2 from P, putida; in every case the tricyclic ketone 5 is transformed with > 96% ee, N-terminal sequences for the FAD/NADPH linked enzymes from Acinetobacter sp,, Pseudomonas sp, and a novel CHMO from R, coprophilus have high homology with each other but no homology with the FMN/NADH linked enzymes; 2,5-DKCMO and 3,6-DKCMO.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Biosciences|
|Depositing User:||R.F. Xu|
|Date Deposited:||27 May 2009 13:55|
|Last Modified:||27 May 2009 13:55|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/19279 (The current URI for this page, for reference purposes)|
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