Holder, S.J. and Jones, R.G. and Benfield, R.E. and Went, M.J. (1996) Wurtz synthesis of a high-molecular-weight organostannane-organosilane copolymer. Polymer, 37 (15). pp. 3477-3479. ISSN 0032-3861.
|The full text of this publication is not available from this repository. (Contact us about this Publication)|
(A)n organosilane-organostannane copolymer of average molecular mass approaching 10 000 Daltons has been prepared by the reaction of dichloromethylphenylsilane and dichloro-n-butylstannane, in a 4.1 molar ratio, with sodium metal in the absence of a solvent. Its subsequent fractionation using hexane led to a product of M(w) = 15 100 with an almost normal distribution (M(w)/M(n) = 2.3) in 11% yield. Nuclear magnetic resonance spectroscopy indicates an Si:Sn molar ratio of 6.2:1.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Biosciences|
|Depositing User:||R.F. Xu|
|Date Deposited:||01 Jun 2009 17:06|
|Last Modified:||01 Jun 2009 17:06|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/19241 (The current URI for this page, for reference purposes)|
- Depositors only (login required):