Connor, J.A. and Charlton, M. and Cupertino, D.C. and Lienke, A. and McPartlin, M. and Scowen, I.J. and Tasker, P.A. (1996) Zinc(II) complexes of putative obligate tetrahedrally co-ordinating pro-ligands. Journal of the Chemical Society-Dalton Transactions (13). pp. 2835-2838. ISSN 0300-9246.
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An attempt to impose tetrahedral geometry on zinc(II) through use of bis(salicylideneamino)biphenyl pro-ligands has produced hydrolytically sensitive complexes. The single-crystal structures of [ZnL(EtOH)] [H(2)L = 6,6'-dimethyl-2,2'-bis(salicylideneamino)biphenyl][monoclinic, space group P2(1)/c, a = 11.654(2), b = 11.753(2), c = 18.878(3) Angstrom, beta = 98.97(2)degrees, Z = 4] and its pro-ligand H(2)L [monoclinic, space group I2/c, a = 13.911(2), b = 13.759(2), c = 12.015(2) Angstrom, beta = 94.836(10)degrees, Z = 4] have been determined. The co-ordination geometry at zinc is slightly distorted trigonal bipyramidal.
Q Science > QD Chemistry
|Divisions:||Faculties > Science Technology and Medical Studies > School of Physical Sciences|
|Depositing User:||M.A. Ziai|
|Date Deposited:||15 May 2009 00:40|
|Last Modified:||15 May 2009 00:40|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/18889 (The current URI for this page, for reference purposes)|
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