Bastow, T.J. and Hobday, M.E. and Smith, M.E. and Whitfield, H.J. (1996) Solid state NMR characterisation of crystalline Na2O-ZrO2-SiO2 phases. Solid State Nuclear Magnetic Resonance, 5 (4). pp. 293-303. ISSN 0926-2040.
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The NMR interactions of crystalline phases in the system Na2O-ZrO2-SiO2 have been studied by a combination of static and magic angle spinning NMR methods for the first time. A full multinuclear (O-17, Na-23, Si-29 and Zr-91) approach has been employed that allows the phases to be clearly identified. NMR interactions such as Si-29 isotropic chemical shift correlate with the known structural units present. For Na-23 the different sites can often be distinguished on the basis of differing quadrupolar interactions.
|Uncontrolled keywords:||solid state NMR; Na2O-ZrO2-SiO2 phases; NMR interactions; characterisation|
Q Science > QD Chemistry
|Divisions:||Faculties > Science Technology and Medical Studies > School of Physical Sciences|
|Depositing User:||M.A. Ziai|
|Date Deposited:||16 May 2009 15:32|
|Last Modified:||16 May 2009 15:32|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/18807 (The current URI for this page, for reference purposes)|
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