Nordmann, A. and Cheng, Y.B. and Smith, M.E. (1996) Role of nitrides in oxynitride glasses and glass-ceramics: An NMR investigation. Chemistry of Materials, 8 (10). pp. 2516-2522. ISSN 0897-4756.
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| Official URL http://dx.doi.org/10.1021/cm960238f |
Abstract
Crystallization of nitrogen-containing glasses based on the Li2O-Al2O3-SiO2 system produces materials comprised of beta-quartz(ss) and beta-spodumene(ss), with minor amounts of X-phase (Si3Al6O12N2) and silicon oxynitride (Si2N2O). X-ray diffraction and Si-29 and Al-27 magic-angle spinning NMR spectroscopy have been used to study the effect of nitrogen on the thermal stability and atomic distribution of beta-quartz(ss), to monitor the evolution of secondary phases in the Li-Si-Al-O-N system, and to compare the differences between using Si3N4 and AlN as the nitrogen source. Samples containing less than or equal to 4wt % nitrogen and heat-treated at temperatures up to 1300 degrees C were analyzed by XRD to determine their crystallinity and phase content, whereas NMR was able to more clearly elucidate the atomic coordination and Si, Al distribution in the crystal structure.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Physical Sciences |
| Depositing User: | F.D. Zabet |
| Date Deposited: | 11 Jun 2009 10:19 |
| Last Modified: | 11 Jun 2009 10:19 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/18706 (The current URI for this page, for reference purposes) |
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