Synthesis and characterization of tricarbonymolybdenum-functionalized poly(methylphenylsilane)

Wiseman, Andrew J. and Jones, Richard G. and Swain, Anthony C. and Went, Michael J. (1996) Synthesis and characterization of tricarbonymolybdenum-functionalized poly(methylphenylsilane). Polymer, 37 (25). pp. 5727-5733. ISSN 0032-3861. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1016/S0032-3861(96)00410-7

Abstract

The synthesis and characterization of a new metal-functionalized polysilane is reported. Treatment of poly(methylphenylsilane) with Mo(CO)(3)(NC5H5)(3) and BF3.OEt(2) affords the novel copolymer, poly(methylphenylsilane-stat-methyl (eta(6)-phenyltricarbonylmolybdenum)silane). The synthesis and characterization of the model compounds, (eta(6)-phenyltricarbonylmolybdenum)trimethylsilane, 1-phenyl-2-(eta(6)-phenyltricarbonylmolybdenum)tetramethyldisilane and 1,2-di(eta(6)-phenyltricarbonylmolybdenum)tetramethyldisilane, are used to support a full structural characterization of the copolymer. Copyright (C) 1996 Elsevier Science Ltd.

Item Type: Article
Uncontrolled keywords: polysilanes; functionalization; molybdenumtricarbonyl
Subjects: Q Science > Q Science (General)
Divisions: Faculties > Social Sciences > Centre for Professional Practice
Depositing User: P. Ogbuji
Date Deposited: 28 Apr 2009 18:05
Last Modified: 27 May 2014 14:03
Resource URI: http://kar.kent.ac.uk/id/eprint/18586 (The current URI for this page, for reference purposes)
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