Hageman, H.J. (1998) Photoinitiators and photoinitiation, Part 14. N-substituted sulphamic esters of alpha-hydroxymethylbenzoin and alpha-hydroxymethylbenzoin ethers as multifunctional photo-initiators. Journal of Photochemistry and Photobiology a-Chemistry, 117 (3). pp. 235-238. ISSN 1010-6030.
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| Official URL http://dx.doi.org/10.1016/S1010-6030(98)00324-4 ... |
Abstract
Several new N-substituted sulphamic esters of alpha-hydroxymethylbenzoin and alpha-hydroxymethylbenzoin ethers have been synthesized. They are shown to release acids on irradiation, and hence to be capable of inducing the acid-catalyzed crosslinking of a melamine resin. They are also shown to photoinitiate the polymerization and crosslinking of acrylates, in all likelihood by the generation of reactive benzoyl and benzoylmethyl radicals, as concluded from a comparison with corresponding sulphonic esters of a-hydroxymethylbenzoin and its ethers.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Physical Sciences |
| Depositing User: | R.F. Xu |
| Date Deposited: | 26 Oct 2009 19:33 |
| Last Modified: | 26 Oct 2009 19:33 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/17792 (The current URI for this page, for reference purposes) |
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