Lutsen, L. and Jones, R.G. (1998) Synthesis and characterization of poly(methylphenylsilylene) poly(methyl methacrylate) block copolymers. Polymer International, 46 (1). pp. 3-10. ISSN 0959-8103.
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Abstract
Block copolymers of poly(methylphenylsilylene) and poly(methyl methacrylate) have been synthesized by condensation of alpha,omega-dichloropoly(methylphenylsilylene) with poly(methyl methacrylate)-lithium. The alpha,omega-dichloropoly(methylphenylsilylene) was synthesized by the Wurtz-type reductive coupling of dichloromethylphenylsilane using sodium in boiling toluene and poly(methyl methacrylate)-lithium was prepared by anionic polymerization of methyl methacrylate in tetrahydrofuran initiated by alpha-methylstyrene-lithium/LiCl. The structures of the block copolymers have been confirmed using size exclusion chromatography and NMR spectroscopy. (C) 1998 SCI.
| Item Type: | Article |
|---|---|
| Additional information: | Special Issue: First Reports from the ARPEGE Network |
| Uncontrolled keywords: | poly(methylphenylsilylene); poly(methyl methacrylate); block copolymer |
| Subjects: | Q Science |
| Divisions: | Faculties > Science Technology and Medical Studies > School of Physical Sciences |
| Depositing User: | M.A. Ziai |
| Date Deposited: | 03 Apr 2009 00:28 |
| Last Modified: | 03 Apr 2009 00:28 |
| Resource URI: | http://kar.kent.ac.uk/id/eprint/17429 (The current URI for this page, for reference purposes) |
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