Poly(methylphenylsilylene)-block-polystyrene copolymer prepared by the use of a chloromethylphenyl end-capped poly(methylphenylsilylene) as a macromolecular initiator in an atom transfer radical polymerisation of styrene

Lutsen, Laurence and Cordina, Gerard P.-G and Jones, Richard G. and Schue, Francois (1998) Poly(methylphenylsilylene)-block-polystyrene copolymer prepared by the use of a chloromethylphenyl end-capped poly(methylphenylsilylene) as a macromolecular initiator in an atom transfer radical polymerisation of styrene. European Polymer Journal, 34 (12). pp. 1829-1837. ISSN 0014-3057. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1016/S0014-3057(98)00041-X

Abstract

Block copolymers of poly(methylphenylsilylene) and poly(styrene) have been conveniently synthesised by using alpha,omega-di((chloromethyl)phenylethyl-dimethylsilyl)poly(methylphenyl silylene) as a macromolecular initiator for the bulk polymerisation of styrene in an atom transfer radical polymerisation reaction. Where appropriate, the structures of the precursor and the block copolymers have been confirmed using size exclusion chromatography and NMR spectroscopy. (C) 1998 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Subjects: Q Science
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences
Depositing User: M.A. Ziai
Date Deposited: 03 Apr 2009 00:34
Last Modified: 27 May 2014 14:13
Resource URI: http://kar.kent.ac.uk/id/eprint/17428 (The current URI for this page, for reference purposes)
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