Addition of nucleophiles to electron-deficient alkenes: structural studies on the incipient reaction and the zwitterionic intermediate

Bell, Paul C. and Wallis, John D. (1999) Addition of nucleophiles to electron-deficient alkenes: structural studies on the incipient reaction and the zwitterionic intermediate. Chemical Communications (3). pp. 257-258. ISSN 1359-7345. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1039/a808488b

Abstract

Three distinct interactions between a Me2N group and an electron-deficient alkene located in the peri positions of a naphthalene ring comprise an almost complete cyclisation, an incipient reaction, and a less favourable orientation of the nitrogen lone pair with respect to the alkene, which can be related to the electronic characteristics of the alkene substituents; the cyclised material is zwitterionic and is composed of the enolate of a beta-dicarboxylic diester and a trialkylarylammonium cation.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences
Depositing User: M. Nasiriavanaki
Date Deposited: 13 Jul 2009 07:30
Last Modified: 17 Jun 2014 11:30
Resource URI: http://kar.kent.ac.uk/id/eprint/17067 (The current URI for this page, for reference purposes)
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