Bastow, T.J. and Botton, G.A. and Etheridge, J. and Smith, M.E. and Whitfield, H.J. (1999) A study of Li2TiOSiO4 and Li2TiOGeO4 by X-ray powder and electron single-crystal diffraction, O-17 MAS NMR and O K-edge and Ti L-2,L-3-edge EELS. Acta Crystallographica Section A, 55 (1). pp. 127-132. ISSN 0108-7673.
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X-ray powder and electron single-crystal diffraction of crystals of Li2TiOSiO4 and Li2TiOGeO4 showed them to be tetragonal, space group P4/nmm unit-cell parameters a = 6.4379(2), c = 4.40032 (2) Angstrom for Li2TiOSiO4 and a = 6.6110(8), c = 4.4372 (6) Angstrom for Li2TiGeO4. The compounds are isostructural with their sodium analogues but are considerably compressed along the c axis owing to the smaller size of lithium compared with sodium atoms. Square-pyramidal TiO5 groups are joined in these compounds by tetrahedral SiO4 and GeO4 groups, respectively. O-17 nuclear magnetic resonance spectra of the two compounds, isotopically enriched with O-17, showed peaks due to the apical titanyl, Ti-O, and basal, bridging, Ti-O-Si or Ti-O-Ge, oxygen atoms of the title compounds. By comparison with reference spectra, oxygen K edges and titanium L-2,L-3 edges of electron energy-loss spectra were tentatively assigned.
|Subjects:||Q Science > QA Mathematics (inc Computing science)
Q Science > QD Chemistry
Q Science > QC Physics
|Divisions:||Faculties > Science Technology and Medical Studies > School of Physical Sciences|
|Depositing User:||M. Nasiriavanaki|
|Date Deposited:||23 Jul 2009 06:23|
|Last Modified:||23 Jul 2009 06:23|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/17057 (The current URI for this page, for reference purposes)|
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