Thermodynamic and kinetic analysis of isothermal microcalorimetric data: applications to consecutive reaction schemes

Gaisford, S. and Hills, A.K. and Beezer, A.E. and Mitchell, J.C. (1999) Thermodynamic and kinetic analysis of isothermal microcalorimetric data: applications to consecutive reaction schemes. In: International Symposium on Calorimetry and Chemical Thermodynamics, Apr 05-09, 1998 , Sao Paulo, Brazil. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1016/S0040-6031(98)00622-4

Abstract

Recent developments have led to a general procedure that allows the analysis of isothermal microcalorimetric data to determine both kinetic and thermodynamic information. Such an analysis means that isothermal microcalorimetry is a powerful technique with which to gain information on a wide range of reactions. Previously, the method of analysis has, principally, been applied to simple, two-stare, solution phase reactions. It is the purpose of the data presented here to show how such an analysis may be applied to solution phase reactions that follow more complex, consecutive reaction pathways using, as a model and example, the acid catalyzed hydrolysis of potassium hydroxylamine trisulfonate.

Item Type: Conference or workshop item (Paper)
Additional information: Issue: 1-2
Uncontrolled keywords: microcalorimetric data; solution phase reactions; thermodynamic analysis
Subjects: Q Science
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences
Depositing User: I.T. Ekpo
Date Deposited: 29 Jun 2011 07:47
Last Modified: 29 Jun 2011 07:47
Resource URI: http://kar.kent.ac.uk/id/eprint/16789 (The current URI for this page, for reference purposes)
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