Rickayzen, G. (1999) The solution of the mean-spherical approximation for the primitive model of electrolytes by a direct method. Molecular Physics, 97 (5). pp. 721-724. ISSN 0026-8976.
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A method introduced by Krienke to derive the Percus-Yevick solution for a fluid of neutral hard spheres is enlarged and used to solve the mean-spherical approximation (MSA) for the primitive model of electrolytes in a direct way. The method exploits the fact that the long range part of the potential is a Green's function. This is used to show that the effect of this part of the potential is merely to introduce a constant into the equations for the short range part of the direct correlation function. These equations can then be solved formally and the new constant can be obtained from an equation previously derived by the author. It is shown, too, that the same method can be used to derive the solution to the MSA for the problem of hard spheres interacting through Yukawa potential tails.
Q Science > QD Chemistry
Q Science > QC Physics
|Divisions:||Faculties > Science Technology and Medical Studies > School of Physical Sciences|
|Depositing User:||F.D. Zabet|
|Date Deposited:||15 Apr 2009 19:32|
|Last Modified:||15 Apr 2009 19:32|
|Resource URI:||http://kar.kent.ac.uk/id/eprint/16542 (The current URI for this page, for reference purposes)|
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