Dodd, A.J., van Eck, Ernst R.H, Jak, M.J.G., Kelder, E.M., Schoonman, J. (2000) NMR study of ionic distribution in Li-doped BPO4. Journal of Solid State Chemistry, 153 (2). pp. 282-286. ISSN 0022-4596. (doi:10.1006/jssc.2000.8759) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:16391)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.dio.org/10.1006/jssc.2000.8759 |
Abstract
Li-7 nuclear magnetic resonance studies of a series of lithium-doped boron phosphates (LixB1-xPO4, 0 < x < 0.2) are reported, Second moment calculations have been made using basic structural models and have been used in conjunction with experimental data to present a model for the distribution of Li ions in the lattice. It is shown that Li ions form in clusters, most likely around a boron vacancy. High-temperature measurements are used to obtain ionic mobility as a function of concentration, and activation energy for hopping of Li ions is shown to increase with concentration, (C) 2000 Academic Press.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1006/jssc.2000.8759 |
| Uncontrolled keywords: | NMR; Li-doped BPO4; second moment; clustering; ceramic electrolyte |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division for the Study of Law, Society and Social Justice > School of Social Policy, Sociology and Social Research |
| Depositing User: | P. Ogbuji |
| Date Deposited: | 27 Mar 2009 13:44 UTC |
| Last Modified: | 16 Nov 2021 09:54 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/16391 (The current URI for this page, for reference purposes) |
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