Interaction between a dimethylamino group and an electron-deficient alkene in ethyl (E)-2-cyano-3-(8-dimethylamino-1-naphthyl)propenoate

Bell, P.C. and Drameh, M. and Hanly, N. and Wallis, J.D. (2000) Interaction between a dimethylamino group and an electron-deficient alkene in ethyl (E)-2-cyano-3-(8-dimethylamino-1-naphthyl)propenoate. Acta Crystallographica Section C-Crystal Structure Communications, 56 (6). pp. 670-671. ISSN 0108-2701. (The full text of this publication is not available from this repository)

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Official URL
http://dx.doi.org/10.1107/S0108270100000512

Abstract

The interaction between the peri substituents in the title compound, C18H18N2O2, measured at 150 K, represents an early stage in the addition reaction of an amino group to an electron-deficient alkene, and has an N ... Csp(2) separation of 2.531 (2) Angstrom; comparison with related structures indicates that the nitrile group activates an alkene to nucleophilic attack more than a coplanar carboxylic ester group.

Item Type: Article
Subjects: A General Works
Divisions: Central Services
Depositing User: P. Ogbuji
Date Deposited: 24 Jun 2009 11:43
Last Modified: 24 Jun 2009 11:43
Resource URI: http://kar.kent.ac.uk/id/eprint/16119 (The current URI for this page, for reference purposes)
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